Advanced Physics questions and answers. An important application of Equation 10.5.15 is the evaluation of Mr; P.J. Flory, N. Rabjohn and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25°C. The molecular weight of the uncross-linked polymer was 225,000, its density was 0. ...Milady Ch. 11 - Nail Product Chemistry Simplified. 20 terms. birdie_lee8. Preview. Chapter 11 Study Guide. Teacher 45 terms. PamperedBeauty. Preview. Answers for 'Self …Thermal properties of cross-linked and uncross-linked low-density polyethylene (LDPE)/Fischer–Tropsch wax blends were investigated in this paper. For cross-linked blends, the gel content was determined. It was observed that the gel content increases with an increase in DCP concentration. The degree of crystallinity decreased with an increase ... an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent skin or eye damage is. a corrosive. a corrosive acid-based primer can cause painful burns and _____________ to soft tissue and eyes. scars. Download scientific diagram | Illustration of the crosslinking process from uncross-linked to cross-linked Insoluble Collagen (IC) using extract-based crosslinking from publication: Extraction of ...Comparative study of cross- and uncross-linked arabinoxylans extracted from maize bran with special reference to their structural and antioxidant potential November 2022 International Journal of ...The effects of the cross-linking time and cross-linker concentration on the viscoelastic properties of the SPI-CH-SAL ternary complex coacervate are shown in Fig. 1.Compared to the uncross-linked ternary complex coacervate, G' and G" of the ternary complex coacervate cross-linked by Ca 2+ decreased significantly (Fig. 1 A). When the …Abstract. Ethylene-propylene-diene-terpolymer (EPDM) and polypropylene (PP)-based uncross-linked and dynamically cross-linked blends were prepared both in an internal …La Crosse Technology is a renowned company that specializes in manufacturing and distributing high-quality weather stations, clocks, and other consumer electronics. With a wide ran...Barrington analyst Kevin Steinke reiterated a Buy rating on Cross Country Healthcare (CCRN – Research Report) today and set a price target... Barrington analyst Kevin Steinke...Question: An important application of Equation 10.5.15 is the evaluation of Mx; P.J. Flory, N. Rabjohn, and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25∘C† The molecular weight of the uncross-linked polymer was 225,000 , its density was 0.92 g/cm3, and the average molecular weight of a1. Introduction. Hyaluronic acid (HA) is a kind of macromolecular anionic polymer existing in the biological body, which is widely used in medicine, the cosmetics …May 23, 2022 · In this study, the preparation and physicochemical properties of cross-linked and uncross-linked hyaluronic acid composite microne were experimentally verified, and the cross-linked and uncross-linked hyaluronic acid composite microne was explored. Opuntia ficus-indica (Cactaceae) is an attractive renewable resource from arid and semi-arid regions of the world, including the north of Africa and Tunisia. It has suitable potential for use as a cellulose source for producing carboxymethyl cellulose (CMC). The chemical composition of fibers obtained from underground (roots) and aerial (trunk) parts of Opuntia ficus-indica, such as cellulose ...where w 0 is the initial weight of the dry sample; w is the weight of the swollen sample; ρ w is the density of the water which was measured after removing the excess liquid on the sample surface by a filter paper and ρ is the density of the dry and uncross-linked gelatin [].. Thermal properties. Differential scanning calorimetry (DSC) …Flow rates of uncross-linked blends are also discussed. The conservation of good mechanical properties of polyethylene and an improvement in the flow rate of the melt was the aim of this work. The ...Chemical cross-linking in combination with mass spectrometric analysis of the created cross-linked products is an emerging technology aimed at deriving …These varieties of cross-linked EPDMs were then compared to an uncross-linked EPDM in terms of density, radius of gyration, free volume, mean square …Yet, the cross-linked nanocomposites exhibited decrements of 6.38–39.53%. This indicates that the gas permeability of PBS was more effectively depressed by the addition of OMLS than by the cross ...In this study, a facile method was developed to prepare the glutaraldehyde (GA) cross-linked collagen/chitosan porous scaffold (S2). The properties of S2 were compared with the scaffolds prepared by the traditional method (S1). Compared to the rough surface and collapsed inner structure of S1, S2 showed a smooth surface and …Sep 27, 2023 · In the realm of nail enhancements, the terms cross-linked and uncross-linked refer to the chemical structure of the enhancements. Specifically, cross-linking describes the process by which polymer chains (the basic building units of the nail enhancer) are linked together into a network, often through covalent bonds. La Crosse Technology is a renowned company that specializes in manufacturing and distributing high-quality weather stations, clocks, and other consumer electronics. With a wide ran...La Crosse Technology is a well-known brand when it comes to sensors and weather monitoring devices. Their range of products includes a variety of sensors that can be used in both r...In today’s digital age, smartphones have become an integral part of our lives. We use them for communication, entertainment, and even productivity. However, there are times when us...The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so it is difficult to maintain the long-term expansion effect in a fixed position. In order to achieve the relatively long-term antiwrinkle effect, a kind of …The divergent nature of chemically and physically cross-linked products tailors them to specific applications. Chemically cross-linked foams feature fine-celled structures, epitomizing toughness and longevity, as seen in materials like cross-linked polyethylene foam and foam rubber. While their rough exterior may lack aesthetic …We present simplified solid phase extraction methods using C 18 /SCX StageTips and mixed-mode OASIS MCX cartridges for a single-step enrichment of cross-linked products prior to LC/MS/MS analysis. Our improved protocols result in 3.5 to 4.6 times higher numbers of cross-link identifications for the model protein bovine serum albumin compared to ...Milady Ch. 11 - Nail Product Chemistry Simplified. 20 terms. birdie_lee8. Preview. Chapter 11 Study Guide. Teacher 45 terms. PamperedBeauty. Preview. Answers for 'Self …Need a cross platform mobile app development company in Poland? Read reviews & compare projects by leading cross platform app developers. Find a company today! Development Most Pop...Compared to uncross-linked products, cross-linked nail enhancements: are more resistant to solvents. All nail adhesives and wraps are based on: cyanoacrylates.Figure 29-2: Schematic representation of the conversion of an uncross-linked thermosetting polymer to a highly cross-linked polymer. The cross-links are shown in a two-dimensional network, but in practice three-dimensional networks are formed. Polymers usually are prepared by two different types of polymerization reactions - addition and ...We would like to show you a description here but the site won’t allow us.The uncross-linked cellulose hydrogels (B0) contained water of 90.8%, while with the incorporation of borax, the water content contained in the cross-linked B1 hydrogels increased to 92.6%.cross-linked with cross-linker DCP is generally greater than that of uncross-linked specimens. Even when the DCP content of cross-linked polyethylene is only 0.5 wt%, the DC breakdown fi eld ...Materials and methods: The effect on proliferative activity in cultures of native cutaneous fibroblasts and keratinocytes was investigated for noncross-linked HA, for noncross-linked HA with added glycerol, for HA that was stabilized in the carboxyl and hydroxyl groups per inner esterification, and for HA that was chemically cross-linked by 1,4 ...The yuan now accounts for 48% of China's cross-border transactions versus 47% for the US dollar. Jump to For the first time ever, the yuan has eclipsed the US dollar as the most us...Meanwhile, at each selected time point from day 3 till day 14, the DNA concentration of PA 0.5 scaffold was significant higher compared to both uncross-linked and GA scaffold, specifically, at day 14, the DNA concentration determined from PA 0.5 scaffold shows significant higher than uncross-linked and GA cross-linked scaffold (P < 0.05), which ...Mar 15, 2023 · The STPP cross-linked coacervates were used as wall materials for Sichuan pepper essential oil (SPEO) encapsulation with encapsulation efficiency of 87.25 %. Compared with uncross-linked microcapsules, cross-linked microcapsules showed higher SPEO retention at high temperature, different pH, and high ionic concentration. The multilayered coatings showed improved corrosion resistance and lower wear rates compared to the single-layer coating and untreated Ti45Nb substrate. ... Cross-linked and uncross-linked CS films with and without HAp reinforcement underwent nano-DMA experimentation. The dynamic loading used in nano-DMA quantifies the time …Thermal, mechanical and dielectric properties of the films are systematically compared. Due to the presence of F atoms and cross-linked structure in polymer chains, these polymeric films exhibit remarkable dielectric properties with the lowest dielectric constant < 2.4 and dissipation factor < 0.003 at frequency from 100 Hz to 1 MHz.Feb 1, 2016 · Increase in Young's modulus as well as the maximum stress is observed in the cross-linked system compared with the uncross-linked chitosan system and CS/HAP nanocomposites. The stress–strain behavior of chitosan system and a system with different percentages of HAP (10%, 20% & 30%) are shown in Fig. 2 (b). cytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering.Fig. 6 is obtained by determining the ratio of elastic deformation to plastic deformation for uncross-linked chitosan and cross-linked chitosan films. According to nanoindentation results, (h max − h f)/h f for uncross-linked and cross-linked chitosan films is around 2.1 and 1.3, respectively. As stated before, these fractions approximate the ...Download scientific diagram | Interfacial polymerization process between PIP and TMC; (a) uncross-linked and (b) cross-linked (3D). from publication: Preparation and characterization of a low ...Jul 1, 2023 · Compared with the uncross-linked ternary complex coacervate, the complex in situ cross-linked with 1.0 % Ca 2+ for 1 h still retains its typical solid characteristics, and has a more compact network structure and better stability. Our research results also showed that prolonging the cross-linking time (from 3 h to 5 h) and increasing the ... The synthesis of GDMA-PMMA resin is carried out by the cross-linking process of GDMA with methyl methacrylate (MMA) through free radical polymerization, in which the GDMA-cross-linked PMMA polymer is acquainted with being an effectual sustenance for solid phase peptide production as illustrated in Figure 1.If you’re in the market for a reliable and efficient vehicle assistance service, OnStar is undoubtedly a name that has crossed your radar. With its range of plans and prices, OnSta...an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent …A comparative study on biodegradation of di-cumyl peroxide (DCP) crosslinked and uncrosslinked natural rubber by Pseudomonas sp. was carried out. Decrease in organic carbon content along with the changes in tensile strength of the treated rubber, both DCP crosslinked and uncrosslinked natural rubber, indicated rubber …The aim of this study was an investigation on the proliferation rate of normal human epidermal keratinocytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL ...The influence of different ratios of alginate and k-carrageenan on the shifting of IR characteristic bands in partially cross-linked products is shown in Fig. 1 b. Each compound is structurally closer to alginate or to k-carrageenan depending on the ratio basis. ... Both uncross-linked and cross-linked composite films have an amorphous ...These varieties of cross-linked EPDMs were then compared to an uncross-linked EPDM in terms of density, radius of gyration, free volume, mean square displacement, and uniaxial tensile stress-strain curves. ... As a product of the cross-linking of atoms at various places, multiple EPDM macromolecular chains with various …Feb 1, 2012 · Shahbikian et al. [24] made a comparative study on the morphology development and the viscoelastic properties of uncross-linked and cross-linked EPDM/PP-based TPEs. The blends were prepared by ... Higher concentrations and longer cross-linking times did not result in a significant increase in the number of cross-linking products obtained. Therefore, a 5 s cross-linking time in 10% formaldehyde was chosen for the following experiments. However, most of the albumin molecules existed in an uncross-linked state. Identification of albumin ligandsIn today’s digital world, it’s essential to have cross-platform compatibility. Being able to access and edit files on different devices is crucial for productivity and convenience....The uncross-linked cellulose hydrogels (B0) contained water of 90.8%, while with the incorporation of borax, the water content contained in the cross-linked B1 hydrogels increased to 92.6%.Thermal, mechanical and dielectric properties of the films are systematically compared. Due to the presence of F atoms and cross-linked structure in polymer chains, these polymeric films exhibit remarkable dielectric properties with the lowest dielectric constant < 2.4 and dissipation factor < 0.003 at frequency from 100 Hz to 1 MHz.The molecular weight of the uncross-linked polymer was 225,000, its density was 0.92 g/cm", and the average molecular weight of a repeat unit was 68. ... of the following samples and compare the calculated value with that obtained from the known fraction of repeat units cross-linked: Fraction cross-linked F/A (Ib-force/in.) 0.005 61.4 0.010 83. ...In this study, a facile method was developed to prepare the glutaraldehyde (GA) cross-linked collagen/chitosan porous scaffold (S2). The properties of S2 were compared with the scaffolds prepared by the traditional method (S1). Compared to the rough surface and collapsed inner structure of S1, S2 showed a smooth surface and …Both Juvéderm ™ products contain unmodified or uncross-linked, free HA. Unmodified HA is included as a lubricant to help decrease extrusion force and make injection easier. Juvéderm ™ Ultra is injected into the mid-dermis via 30-gauge needle while Juvéderm ™ Ultra Plus is implanted deeper via a 27-gauge needle.Final answer: Cross-linked and uncross-linked refer to the chemical structure of nail enhancements. Cross-linked enhancements have linked polymer …When it comes to building a new home, one of the most important factors to consider is the cost per square foot. This is a crucial metric that helps homeowners understand how much ...Maxium Barrault wanted to implement Jerry Seinfeld's productivity secret of forming a chain by crossing off the calendar every day, but apps like Habit Streak Plan weren't doing it...Purpose To evaluate the 36 months changes in posterior corneal surface parameters in keratoconic eyes after accelerated corneal cross-linking and to compare the data with uncross-linked progressive and non-progressive keratoconic eyes. Methods Thirty five cross-linked, 30 uncross-linked progressive, and 30 uncross-linked non …Study with Quizlet and memorize flashcards containing terms like Most chemicals are: A) deadly B) dangerous to touch C) dangerous to ingest D) completely safe, Everything you …Biodegradable blends of potato starch and polyvinyl alcohol were prepared by solution casting method. Citric acid was employed to introduce the plasticizing effect into the starch materials. Glutaraldehyde as cross-linker was used to enhance the properties of the blend films. Cross-linking is a common method to improve the strength and stability of … cytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering. Although the cross-linked product goes through a crystalline melt point at a temperature similar to uncross-linked resin, it has sufficient melt strength to support …A Vicat analyzer was used to measure the setting times of cement pastes with the presence of cross-linked superplasticizers and uncross-linked superplasticizers. Cement (150 g), deionized water (52.5 g) and superplasticizers (bwoc = 0.2%) were mixed completely and filled into a specific vessel.2.3.. Viscoelasticity measurementsUncross-linked and cross-linked starch–pectin samples (5%, w/v) were prepared in 20 ml sealed screw-capped flasks with deionised water using a motorised stirrer.For gelatinisation of the uncross-linked blends, the polysaccharide dispersions were heated to ∼80 °C for 20 min under continuous …Q14. Overfiling the nail can lead to free-edge product separation, which is also known as: curling. speckling. splintering. chipping. 300 s. Q15. Proper preparation of the nail plate for nail enhancements includes removing all dead tissue from the side walls and _____________ as well as bacteria, oil and moisture from the nail plate.Apr 22nd, 2021. Jet injection of HA resulted in significant skin improvement with minimal downtime, pain and side effects. Researchers Diane MacGillis, MD, and Yuri Vinshtok, MD, investigated the clinical efficacy of non-crosslinked hyaluronic acid (NCL-HA) and crosslinked hyaluronic acid (CL-HA) for aesthetic skin concerns when delivered ...Our results from nanoindentation and microhardness tests have shown that cross-linked chitosan films significantly improve the elastic modulus compared to …Higher concentrations and longer cross-linking times did not result in a significant increase in the number of cross-linking products obtained. Therefore, a 5 s cross-linking time in 10% formaldehyde was chosen for the following experiments. However, most of the albumin molecules existed in an uncross-linked state. Identification of albumin ligandscomparison of Λ between this lightly cross-linked system and uncross-linked system, a linear relation between ln Λ and ε is assumed as in the case of uncross-linked system. The solid line in Fig.7 is calculated by the least squares method, and the slope of the line is shown in the figure. Comparing withThe cross-linking structure of the Ethylene-propylene-diene monomer (EPDM) is made up of a number of cross-linking types, including carbon atoms from the main chain or monomer and ether crosslinks formed during degradation. Through molecular dynamic simulations, the contribution of each type of cross-linked structure to the …Compared to uncross-linked products, cross-linked nail enhancements are _____ to solvents. More resistant . All nail adhesives and wraps are based on ... When your clients fingertips are soaking in a container of acetone to aid the removal of a nail enhancement product, it is recommended that you cover the container with _____. A clean terry ...The uncross-linked cellulose hydrogels had a swelling ratio of 325%, while the swelling ratio of the cross-linked hydrogels could achieve ~ 900%. With increasing …Cross-linked polymer-like bulk gel used in water shutoff has very poor flowability; the viscosity is very high (>10,000 mPa·s). Uncross-linked polymer is used to increase water viscosity. A movable gel is used in between; it has the intermediate viscosity, and more importantly, it can flow under some pressure gradient.When it comes to purchasing Fud chorizo, there are a few key factors to consider in order to get the best value for your money. From comparing prices at different stores to evaluat...Hylan cross-linked with formaldehyde shows an enormous capacity to bind water, and even at 10 g water to 1 g hylan, almost all the water is retained either in the freezing-bound or non-freezing state. Cross-linked hylan Hylan gel is even more effective, retaining up to 15 g water to 1 g hylan in the freezing bound state.The cell size distribution, cell diameter, cell density, volume expansion ratio, and foaming rate of radiation-cross-linked polypropylene under different foaming conditions were analyzed and compared.Question: An important application of Equation 10.5.15 is the evaluation of Mx; P.J. Flory, N. Rabjohn, and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25∘C† The molecular weight of the uncross-linked polymer was 225,000 , its density was 0.92 g/cm3, and the average molecular weight of aYet, the cross-linked nanocomposites exhibited decrements of 6.38–39.53%. This indicates that the gas permeability of PBS was more effectively depressed by the addition of OMLS than by the cross ...PRC and final D worsened in the cross-linked and progressive uncross-linked groups, and did not change in the non-progressive group. Conclusion: Despite a decreased K max , the posterior corneal surface parameters, posterior elevation values were determined to have significantly worsened in the cross-linked group and this increase was higher ...Apr 16, 2024 · The divergent nature of chemically and physically cross-linked products tailors them to specific applications. Chemically cross-linked foams feature fine-celled structures, epitomizing toughness and longevity, as seen in materials like cross-linked polyethylene foam and foam rubber. While their rough exterior may lack aesthetic appeal, it ... These varieties of cross-linked EPDMs were then compared to an uncross-linked EPDM in terms of density, radius of gyration, free volume, mean square displacement, and uniaxial tensile stress-strain curves. ... As a product of the cross-linking of atoms at various places, multiple EPDM macromolecular chains with various …Meanwhile, at each selected time point from day 3 till day 14, the DNA concentration of PA 0.5 scaffold was significant higher compared to both uncross-linked and GA scaffold, specifically, at day 14, the DNA concentration determined from PA 0.5 scaffold shows significant higher than uncross-linked and GA cross-linked scaffold (P < 0.05), which ...Adjustment of the β-casein content was achieved by blending uncross-linked or cross-linked β-casein poor solution with uncross-linked β-casein rich solution in ratios of 70:30, 80:20, 90:10, or 100:0, with 90:10 roughly corresponding to the status of the original skim milk (this was estimated from the weight of the achieved powders).
The effect of cross-linking on the secondary structure of crystalline HSA has been studied by FTIR spectroscopy. The second derivative of FTIR spectra of uncross-linked crystals, lCLPC–HSA and hCLPC–HSA were compared in the amide I region after area normalization and curve fitting (Fig. 3).. Malenia scarlet rot
The aim of this study was an investigation on the proliferation rate of normal human epidermal keratinocytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering. Nanofibrous scaffolds were prepared by electrospinning of different …The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so ...Properties of cross-linked (PEX) and uncross-linked PE [1]. ... Comparison of Cross-Linking Methods. In summary, thermoplastics are cross-linked industrially by either irradiation or by application of peroxide or silane grafting reagents. ... Although the cross-linked product goes through a crystalline melt point at a temperature similar to ...Rationale: Chemical cross-linking in combination with a mass spectrometric analysis of the created cross-linked products is an area of growing interest for deriving low-resolution structural information of proteins and protein complexes. One of the greatest challenges is the complexity of the created cross-linking mixtures, which can be met by ...Jul 1, 2023 · Compared with the uncross-linked ternary complex coacervate, the complex in situ cross-linked with 1.0 % Ca 2+ for 1 h still retains its typical solid characteristics, and has a more compact network structure and better stability. Our research results also showed that prolonging the cross-linking time (from 3 h to 5 h) and increasing the ... Download scientific diagram | Crystallization exotherms of the uncross-linked and cross-linked materials from publication: Effect of organoclay content on mechanical and rheological properties of ...In this research, oxidized sucrose, a novel aldehyde-based green cross-linker, endowed starch films with substantial improvement in both tensile strength and elongation, whereas many other cross-linkers did not. Starch films are usually weak, brittle, and highly moisture sensitive, and thus have restricted industrial applications. Cross-linking is one of the …Study with Quizlet and memorize flashcards containing terms like Most chemicals are: A) deadly B) dangerous to touch C) dangerous to ingest D) completely safe, Everything you can see or touch, except ___, is a chemical. A) water and wood B) light and electricity C) light and water D) electricity and wood, It is possible to chemically convert ___ into ___. A) acetone; oxygen B) paper; sugar C ...Apr 1, 2004 · Here, we describe the isolation and characterisation of carboxy-terminal telopeptide structures of type I collagen from human mineralised bone. Analysis of the collagen cross-links within the purified structures indicated the presence of trivalent ICTP structures, divalently cross-linked peptides and uncross-linked telopeptide chains. Chemistry. Chemistry questions and answers. An important application of Equation 10.5.15 is the evaluation of M.; P.J. Flory, N. Rabjohn, and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25°C. The molecular weight of the uncross-linked polymer was 225,000, its density ... Question: An important application of Equation 10.5.15 is the evaluation of Mx; P.J. Flory, N. Rabjohn, and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25∘C† The molecular weight of the uncross-linked polymer was 225,000 , its density was 0.92 g/cm3, and the average …Aug 1, 1995 · @article{AlAssaf1995TheES, title={The enhanced stability of the cross-linked hylan structure to hydroxyl (OH) radicals compared with the uncross-linked hyaluronan}, author={Saphwan Al-Assaf and Glyn O. Phillips and David J. Deeble and Barry J. Parsons and H James Starnes and Clemens von Sonntag}, journal={Radiation Physics and Chemistry}, year ... Feb 1, 2012 · Shahbikian et al. [24] made a comparative study on the morphology development and the viscoelastic properties of uncross-linked and cross-linked EPDM/PP-based TPEs. The blends were prepared by ... We would like to show you a description here but the site won’t allow us.a subunit in the cross-linked product. Cross-linked Go can be ADP-ribosylated by pertussis toxin. This ADP- ribosylation is inhibited by GTPrS with a concentra- tion dependence that is indistinguishable from that of the control, uncross-linked Go. These two kinds of ex- periments indicate that a, is able to change its confor- mation even though ... an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent skin or eye damage is. a corrosive. a corrosive acid-based primer can cause painful burns and _____________ to soft tissue and eyes. scars. .
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